Xenon Difluoride

The Xetch® uses Xenon Difluoride as the etching gas. Xenon difluoride exhibits a high selectivity to silicon versus many materials. Xenon difluoride is also widely available. See our overview of the unique advantages of XeF2 etching.

Xenon Difluoride Advantages

  • Selectivity during etching
    XeF2 shows very high selectivity vs silicon to the majority of semiconductor materials including photoresist, silicon dioxide, silicon nitride, and aluminum. Typically the selectivity of silicon nitride is better than 100:1 and the selectivity to silicon dioxide is better than 1000:1.
  • No release stiction
    XeF2 etching is a dry process so no drying is needed which avoids the sticking issues that often plague wet release processes.
  • Delicate structures are safely released
    Since XeF2 etching is a dry, room temperature process delicate structures can be released. This is particularly useful for releasing delicate devices, such as micromirrors, that are best released after dicing and wire bonding.

Pricing and Availability

XACTIX maintains and updates a list of suppliers of xenon difluoride.

Physical Properties

Density 4.32
MW 169.290
MP 130-135°C
FP none
Vapor Pressure 3.9 Torr (room temperature)

Safety

All XACTIX equipment uses sealed XeF2 cylinders along with software-guided cylinder change procedures so using XeF2 is easy. An additional advantage of XeF2 is that it is a solid at room temperature and pressure which makes safe handling easier than many pressurized etching gases. For further information refer to the Material Safety Data Sheets below.

Material Safety Data Sheet (MSDS) from Air Products

Material Safety Data Sheet (MSDS) from Pelchem